{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-dimethylhydrazine-κ2 P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
نویسندگان
چکیده
The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol-ecule exhibits a twofold rotation axis.
منابع مشابه
{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ2 P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H⋯Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further atta...
متن کامل[μ-1,2-Bis(diphenylphosphanyl)-1,2-diethylhydrazine-κ2 P:P′]bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(28)H(30)N(2)P(2))]·2C(4)H(8)O, was synthesized from a bidentate phosphine ligand complexed to two linear gold(I) chloride moieties. The Au(I) atom is in an almost linear coordination with a P-Au-Cl angle of 179.22 (4)°. The complex molecules reside on a twofold rotation axis.
متن کامل[μ-1,2-Bis(diphenylphosphanyl)-1,2-dimethylhydrazine-κ2 P:P′]bis[chloridogold(I)]
The title compound, [Au(2)Cl(2)(C(26)H(26)N(2)P(2))], is formed from a bidentate phosphine ligand complexed to two linearly coordinated gold(I) atoms. The gold(I) atoms are 3.4873 (7) Å apart. The mol-ecule exhibits a crystallographic twofold rotation axis.
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In the title compound, [Ni(2)(C(2)H(4))(2)(C(25)H(22)P(2))(2)]·2C(7)H(8), each Ni atom is coordinated in a trigonal-planar geometry by two P atoms of the bridging 1,2-bis-(diphenyl-phosphino)methane (dppm) ligands and by the centroid of the double bond of an ethene ligand. An eight-membered ring comprising the two Ni atoms, four P atoms and the CH(2) groups of the two dppm ligands is thus forme...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011